Ichigo and his friends arrive in Hueco Mundo to confront Quilge Opie and learn that their latest enemy are Quincies.

Shigekuni Genryusai Yamamoto learns that the Yhwach he defeated was an impostor. The real Yhwach then reveals himself and easily kills Genryusai, sending a wave of shock and devastation across the Soul Reapers.

Kenpachi Zaraki removes his eye patch to fight Retsu Unohana, a.k.a. Yachiru Unohana, “The First Kenpachi.” Meanwhile, Ichigo and Renji head to Hoohden to meet Oh-Etsu Nimaiya, the man who is said to have created the Zanpakuto.

Kensei Muguruma joins the battle against Masculine, who has already defeated Shuhei Hisagi, Ikkaku Madarame, and Yumichika Ayasegawa. However, Kensei is taken aback by how weak his opponent is.

Yhwach finally steps through the main entrance of the Royal Palace. Accompanied by Haschwalth and Uryu, the Quincy King is preparing to advance toward the Greater Palace when they are stopped by Senjumaru Shutara of Squad Zero.

Yhwach performs Auswählen to bestow power to his fallen Royal Guards and activate their Voll Stern Dich forms. What follows is a fierce battle between the Royal Guards and Squad Zero.